Sunday, November 10, 2013

Blog Entry 11/10/13

This week in AP Chemistry, we focused on state changes. We started off with some discussion on liquids and solids, and also what it looked like when potassium chloride was dissolved in water. Water is a polar molecule, so when the individual K and Cl ions are broken off, they are surrounded by water molecules and are said to be hydrated. K is a cation, so the water molecules orient themselves so that the more electronegative O atom is pointing towards the ion. For chloride, it’s just the opposite. The partially positive areas of the water molecule, the H atoms, orient themselves so they are pointing towards the chloride anion.

Soap is an everyday necessity. It’s common knowledge that soap is able to clean the grease off of a dish But how does it remove those oils? We discussed this question in class. Soaps are fatty acid chains with hydrocarbon chains. It is a polar molecule, and the hydrophilic part of the chain interacts with water through ion-dipole interactions and hydrogen bonding. The hydrophobic parts curl up into themselves. The chains are attached by dispersion forces and form a spherical surface, which attract the oils and fats on a surface and store them within a sphere.



We also held a brief discussion on why humans aren’t just a mass of liquid or gas by discussing the composition of cell membranes. Cell membranes are made up of phospholipids, a form of fats. These phospholipids form the lipid bilayer, and are composed of a hydrophilic head and hydrophobic tails. Only water and gases can easily pass through this membrane, and large molecules and small polar molecules cannot without the assistance of proteins.

On Tuesday, we whiteboarded what was in the bubbles that come out of boiling water. The bubbles contain water vapor, which is water in its gaseous form. We also went over the IMF and Solids POGIL.



On Friday, we performed a minilab where we were given mystery substances, and based on their properties, we were to decipher which substance it was. The first part of the lab involved testing the electrical conductance of given substances (water, ethanol, acetone, nonane, sodium chloride, steel, and sucrose). We used conductance testers and immersed them in the liquid states of the substances, and also tested the conductance of the dissolved and solid states of the substances. For the substances that weren’t able to be simulated in a certain state (such as molten steel) , we used a QR code to view videos that tested the conductance of these substances. We found that the ionic substance NaCl was an insulator in its solid state, but became a good conductor of electricity when it was dissolved in water.

The second part of the minilab involved observing the properties of different substances and trying to name them. We swirled the liquids to test their viscosity. Glycerin was quite easy to find; it was easily the most viscous due to its three hydroxyl groups. We also tested the evaporation rate and surface tension of the substances, and tried to see if one substance was soluble in another. Acetone evaporated extremely quickly due to its weak intermolecular London dispersion forces.

This lab was very helpful in observing how a molecule’s composition affects its properties. It all depends on the intermolecular forces. The stronger the intermolecular force, the slower a substance will evaporate and the more viscous it will be.



Sunday, November 3, 2013

Blog Entry 11/3/13

This week in AP Chemistry, we started off by pondering the effects of the charge and size of an ion on melting and boiling points. We were given a question on the projector screen along with a few choices. Without any discussion with our tablemates, we voted on the choice we found most correct. It was quite similar to the Socrative website we used earlier in the tri. After voting individually, we discussed the question with our tablemates and came up with an answer we all agreed on. Many times, there was a wide variety of answer preference. Other times, however, there was dispute between two choices. I particularly remember having a very engaging discussion about one of the questions, and our table ended up being split in half on what answer we thought was correct. After our table discussion, we saw the correct answer and discussed why the other choices would not have been correct. Coulomb’s law was especially important when thinking of the solution.

The ConcepTest was quite helpful for me, and I hope we do more in the future. The discussions I had with my tablemates really helped me view different ways of approaching a problem, and based on their logic, I often changed my answer when I felt their explanation was more reasonable.

On Tuesday, we started a new POGIL on intermolecular forces. My experience in Latin class already gave me some prerequisite knowledge on the subject, the Latin word “inter” means between, so I assumed that intermolecular forces were forces between molecules. “Intra” means within, and those are the forces within a molecule. We had dealt mostly with intramolecular forces before this week during our covalent bonding unit.

In the middle of the week, we explored why ice is slippery. We all know that it’s difficult to walk on an icy surface without our feet slipping out from underneath us, but we were baffled when asked why this is so. We explored the question at the molecular level by using models of water molecules and simulating the structures of ice and water. When we created the molecular structure of ice, which is a ring-like structure filled with many gaps, it took up a lot of space. This explains why when water is frozen, it expands in the container it is in.

We used our hands to represent the pressure of an ice skater’s blade on the surface of ice. When we pushed down on the ice structure with our hands, the structure collapsed and assumed the structure of water again. Basically, when a skater’s blade makes contact with the ice, the molecules directly under the blade turn into water and cause the ice to be slippery.



Due to catching the nasty cold that has been going around the school, I was unable to attend class on Thursday and Friday. However, I heard we whiteboarded much of the intermolecular forces POGIL and I also stayed caught up by watching the lectures and completing the lecture quizzes. We discussed liquids and solids, and also further discussed intermolecular forces, the strongest of which is hydrogen bonding.